Download PDF by Peter Auer and David Douglas (Eds.): Advances in Energy Systems and Technology. Volume 4

By Peter Auer and David Douglas (Eds.)

ISBN-10: 0120149044

ISBN-13: 9780120149049

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So putting d[nA2]/dt = 0 and if [] = []e ([]e is the equilibrium value) one finds W * r e c = [lA]c/[rtA2]e = ^üe a i l d K Ue = K Ue^ ^ where K[]e is the equilibrium constant expressed in terms of the molar concentrations. Because of this relationship between &diss and krec at equilibrium, usually only one of these rates is measured, the other being inferred using equilibrium constant data. There are cases where this procedure might be suspect; however for our purposes, it is ade­ quate. We can now rewrite the kinetic equation as follows, d[nA2]/dt = krtc[nx][nA2\([nA]2/[nA2] - kdiJkrec) (8) or, using the equilibrium relation d[nA2]/dt = krcc[nx][nA2]([nA]2/[nA2] - [nA]l/[nA2]e) (9) One can define the ratio [nA]2/[nA2] as Κ^ , which has the form of an equilibrium constant but using the actual concentrations present in the nonequilibrium situation.

Title 29-Labor, Parts 19001919, p. 576. Revised as of July 1, 1979. S. C. Watts, R. G. (1979). Reconciling zero- and one-dimensional climate models. Unpublished manuscript. Watts, R. G. (1980). Climate models and C02-induced climatic changes. Clim. Change 2, 387-408. Wittwer, S. H. (1978). Carbon dioxide fertilization of crop plants. In "Crop Physiology" (U. S. ), pp. 310-333. Oxford and IBH Publishing Company, New Delhi, India. Wittwer, S. H. (1980). Carbon dioxide and climatic change: An agricul­ tural perspective.

Res. 88(C2), 1301-1308. Rust, B. , Rotty, R. , and Marland, G. (1979). Inferences drawn from atmospheric C0 2 data. / . Geophys. Res. 84(C6), 31153122. Schneider, S. , and Thompson, S. L. (1981). Atmospheric C0 2 and climate: Importance of the transient response. J. Geophys. Res. 86(C4), 3135-3147. Sommer, A. (1976). Attempt at an assessment of the world's tropical moist forests. Unasylva 28, 5-24. Strain, B. , ed. (1978). " Duke University, Duke Environmental Center, Durham, North Caro­ lina. , ed.

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Advances in Energy Systems and Technology. Volume 4 by Peter Auer and David Douglas (Eds.)


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